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Original Articles

Unexpected Racemization of 2-Hydroxymethylphenylphosphine Oxides

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Pages 249-253 | Received 15 Sep 2012, Accepted 23 Oct 2012, Published online: 08 May 2013
 

Abstract

2-Hydroxymethylphenylphosphine oxides undergo partial racemization in the reaction with mesyl anhydride or mesyl chloride. A possible mechanism is discussed.

GRAPHICAL ABSTRACT

Acknowledgments

Financial support by the Polish Ministry of Science and Higher Education, Grant No N204 131140 (for Piotr Kiełbasiński) and by CMMS PAS, grant 551-23 for PhD students (for S. Kaczmarczyk), is gratefully acknowledged.

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