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Original Articles

Reaction of Sulfinic Acids with Heteroconjugated Alkenes

Pages 1670-1674 | Received 16 May 2012, Accepted 15 Dec 2012, Published online: 20 Sep 2013
 

Abstract

The nucleophilic addition reactions of arenesulfinic acids with heteroconjugated alkenes have been studied. The structures of the sulfones thus obtained were confirmed by microanalytical and spectral methods. Kinetic parameters of the nucleophilic addition reactions were determined. Interactions are second-order reactions, but they are first order regarding each reagent. The influence of various substituents at the carbon–carbon double bond on the nucleophilic activity was studied.

GRAPHICAL ABSTRACT

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