Abstract
An overview of 2-phosphaindolizines, i.e. 1,3-azaphospholo[1,5-a]pyridines along with their 1-aza-, 3-aza- and 1,3-diaza analogues has been presented. It includes their methods of syntheses, characterization and reactions. Under reactions, electrophilic substitutions, N-alkylation, Diels-Alder (DA) reactions with the >C=P- functionality in the absence of the catalyst and also in the presence of the catalyst, other 1,2-additions across the >C=P- functionality, cheletropic cycloaddition of tetrachloro-o-benzoquinone (TCQ) with the phosphorus atom and co-ordination with the metal pentacarbonyls and other derivatives have been described.
GRAPHICAL ABSTRACT
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