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Phosphorus, Sulfur, and Silicon and the Related Elements Volume 189, 2014 - Issue 7-8: Special Issue Dedicated to Louis D. Quin
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Original Articles

The Superbulky Pn Ligand Complexes [CpBIGFe(η5−P5)] and [(CpBIGFe)2(μ,η4:4-P4)]—Synthesis and Characterization

Sebastian HeinlInstitut für Anorganische Chemie, Universitätsstraße 3193053, RegensburgView further author information
,
Gábor BalázsInstitut für Anorganische Chemie, Universitätsstraße 3193053, RegensburgView further author information
&
Manfred ScheerInstitut für Anorganische Chemie, Universitätsstraße 3193053, RegensburgCorrespondence[email protected]
View further author information
Pages 924-932 | Received 20 Jan 2014, Accepted 21 Feb 2014, Published online: 04 Aug 2014
 
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Abstract

A new synthesis of [CpBIGFe(CO)2]2 3 (CpBIG = C5(4-nBuC6H4)5) was developed starting from CpBIGNa and FeCl2 in the presence of CO. Reaction of this product with P4 leads to the two new Pn ligand complexes [CpBIGFe(η5-P5)] 1b and [(CpBIGFe)2(μ,η4:4-P4)] (4) containing the highly sterically demanding CpBIG ligand. Depending on the solvent, different ratios of 1b:4 are obtained. The products 1b, 3, and 4 were characterized by spectroscopic methods as well as by X-ray diffraction.

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Funding

This work was supported by the Deutsche Forschungsgemeinschaft (DFG). Sebastian Heinl gratefully acknowledges the Fonds der Chemischen Industrie for a PhD fellowship.

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