Optically Active T-Butylphenylphosphinothioic Acid: Synthesis, Selected Structural Studies and Applications as a Chiral Solvating Agent

Józef DrabowiczCenter of Molecular and Macromolecular Studies, Polish Academy of Sciences, Department of Heteroorganic Chemistry, Sienkiewicza, Poland;Jan Dlugosz University in Czestochowa, Institute of Chemistry, Environmental Protection and Biotechnology, Czestochowa, PolandCorrespondence[email protected]

Patrycja Pokora-SobczakCenter of Molecular and Macromolecular Studies, Polish Academy of Sciences, Department of Heteroorganic Chemistry, Sienkiewicza, Poland

Dorota KrasowskaCenter of Molecular and Macromolecular Studies, Polish Academy of Sciences, Department of Heteroorganic Chemistry, Sienkiewicza, Poland

Zbigniew CzarnockiFaculty of Chemistry, Warsaw University, Warsaw, Poland

Abstract

Synthesis, structural studies and the use of the (−)-(S)- and (+)-(R) enantiomers of t-butylphenylphosphinothioic acid as a chiral solvating agent for the determination of enantiomeric purity is discussed. Systems that are the most extensively studied are emphasized.

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Optically Active T-Butylphenylphosphinothioic Acid: Synthesis, Selected Structural Studies and Applications as a Chiral Solvating Agent

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Optically Active T-Butylphenylphosphinothioic Acid: Synthesis, Selected Structural Studies and Applications as a Chiral Solvating Agent

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