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Phosphorus, Sulfur, and Silicon and the Related Elements Volume 190, 2015 - Issue 3
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Original Articles

A Ladder-Like Five-Coordinated Zinc Coordination Polymer Based On 2-Carboxyethyl(Phenyl)Phosphinic Acid and 1,10-Phenanthroline

Lei GuanSchool of Chemistry and Materials Science, Liaoning University of Petroleum and Chemical Engineering, Fushun, 113001, ChinaCorrespondence[email protected]
,
Hua Fei ShengSchool of Chemistry and Materials Science, Liaoning University of Petroleum and Chemical Engineering, Fushun, 113001, China
&
Ying WangCenter of Experiment, College of Chemistry, Chemical Engineering and Environmental Engineering, Liaoning University of Petroleum and Chemical Engineering, Fushun, 113001, China
Pages 372-379 | Received 31 Mar 2014, Accepted 16 Jul 2014, Published online: 25 Feb 2015
 
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GRAPHICAL ABSTRACT

Abstract

A one-dimensional ladder-like five-coordinated zinc coordination polymer, [Zn(ceppa)(phen)·5H2O]n (ceppa = 2-carboxyethyl(phenyl)phosphinate; phen = 1,10-phenanthroline) was hydrothermally synthesized in a mixed solvent system, where ethanol was used as the co-solvent.The as-synthesized product was characterized by a single-crystal X-ray diffraction technique, elemental analysis, ICP-AES, NMR, FTIR, UV-Vis spectrum, and thermo-gravimetric analysis. The one-dimensional ladder-like structure is constructed of 8-membered ring [Zn(PO2)]2 and 14-membered ring [(PO)CH2CH2COZn]2. Moreover, it is noticeable that π–π stacking interactions exist between 1,10-phenanthroline molecules of the adjacent one-dimensional chains in the same layer, and between benzene rings and 1,10-phenanthroline molecules. Additionally, the complex exhibits the photoluminescence with an emission maximum at 383 nm at room temperature.

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