Mild, Selective, and Efficient Oxidation of Sulfides to Sulfoxides Catalyzed by Mn(Iii)-Salen Complexes

Alessandro BismutoDipartimento di Scienze Chimiche, Università di Napoli “Federico II”, Complesso Universitario Monte S. Angelo, Via Cintia, I-80126, Napoli, Italy

Maria E. CucciolitoDipartimento di Scienze Chimiche, Università di Napoli “Federico II”, Complesso Universitario Monte S. Angelo, Via Cintia, I-80126, Napoli, Italy;Consorzio Interuniversitario di Reattività Chimica e Catalisi, via Celso Ulpiani 27 70126, Bari, Italy

Francesco RuffoDipartimento di Scienze Chimiche, Università di Napoli “Federico II”, Complesso Universitario Monte S. Angelo, Via Cintia, I-80126, Napoli, Italy;Consorzio Interuniversitario di Reattività Chimica e Catalisi, via Celso Ulpiani 27 70126, Bari, ItalyCorrespondence[email protected]

Aldo VitaglianoDipartimento di Scienze Chimiche, Università di Napoli “Federico II”, Complesso Universitario Monte S. Angelo, Via Cintia, I-80126, Napoli, Italy;Consorzio Interuniversitario di Reattività Chimica e Catalisi, via Celso Ulpiani 27 70126, Bari, Italy

Massimiliano CurcioInstitute for Polymers, Composites and Biomaterials (IPCB), National Research Council of Italy (CNR), P.le Fermi 1, I-80055Portici, Napoli, Italy

GRAPHICAL ABSTRACT

Abstract

A detailed optimization of the catalytic environment for the oxidation of sulfides promoted by Mn(salen)/H₂O₂ systems is proposed. The experimental setup is demonstrated to be active towards different substrates, providing TOFs up to 9300 h⁻¹, which are among the highest reported for homogeneous catalysts employed in sulfoxidation reactions.

Keywords:

Reprints and Corporate Permissions

Please note: Selecting permissions does not provide access to the full text of the article, please see our help page How do I view content?

To request a reprint or corporate permissions for this article, please click on the relevant link below:

Order Reprints Request Corporate Permissions

Academic Permissions

Please note: Selecting permissions does not provide access to the full text of the article, please see our help page How do I view content?

Obtain permissions instantly via Rightslink by clicking on the button below:

Request Academic Permissions

If you are unable to obtain permissions via Rightslink, please complete and submit this Permissions form. For more information, please visit our Permissions help page.

Mild, Selective, and Efficient Oxidation of Sulfides to Sulfoxides Catalyzed by Mn(Iii)-Salen Complexes

Information for

Open access

Opportunities

Help and information

Mild, Selective, and Efficient Oxidation of Sulfides to Sulfoxides Catalyzed by Mn(Iii)-Salen Complexes

GRAPHICAL ABSTRACT

Abstract

Reprints and Corporate Permissions

Academic Permissions

Related research

To cite this article:

Download citation

Information for

Open access

Opportunities

Help and information

Keep up to date

Your download is now in progress and you may close this window

Login or register to access this feature