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Phosphorus, Sulfur, and Silicon and the Related Elements Volume 190, 2015 - Issue 5-6: 20th International Conference on Phosphorus Chemistry (ICPC-2014)
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Original Articles

The Air-Stable P-Heterocyclic Biradical for OFET Devices

Shigekazu ItoDepartment of Applied Chemistry, Graduate School of Science and Engineering, Tokyo Institute of Technology, Ookayama, Meguro, Tokyo, JapanCorrespondence[email protected]
,
Yasuhiro UetaDepartment of Applied Chemistry, Graduate School of Science and Engineering, Tokyo Institute of Technology, Ookayama, Meguro, Tokyo, Japan
,
Yushi TorihataDepartment of Applied Chemistry, Graduate School of Science and Engineering, Tokyo Institute of Technology, Ookayama, Meguro, Tokyo, Japan
&
Koichi MikamiDepartment of Applied Chemistry, Graduate School of Science and Engineering, Tokyo Institute of Technology, Ookayama, Meguro, Tokyo, Japan
Pages 854-857 | Received 27 Aug 2014, Accepted 21 Oct 2014, Published online: 01 Jul 2015
 
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GRAPHICAL ABSTRACT

Abstract

p-Type organic field-effect transistor (OFET) property of the air-stable 1,3-diphosphacyclobutane-2,4-diyl was preliminarily characterized and discussed based on the physicochemical properties and the crystal structure.

ACKNOWLEDGMENTS

The authors thank Prof. J.-i. Nishida, University of Hyogo, and Prof. Yoshiro Yamashita, Tokyo Institute of Technology, for supporting the OFET study. Mr. Makoto Kobayashi and Ms. Trang Thi Thu Ngo supported this work. IP was recorded with a Riken Keiki AC-2 spectrometer.

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Related Research Data

A P2C2 Four‐Membered Ring with Unusual Bonding—Synthesis, Structure, and Ring Opening of a 1,3‐Diphosphacyclobutane‐2,4‐diyl
Source: Wiley
Catenation of 1,3‐Diphosphacyclobutane‐2,4‐diyl Units Having 2,4,6‐Tri‐tert‐butylphenyl Protecting Groups and a P‐sec‐Butyl Group in the Ring
Source: Wiley
Exploration of 1-Arylmethyl-1,3-diphosphacyclobutane-2,4-diyls as Hole Transfer Materials
Source: Wiley
CCDC 957263: Experimental Crystal Structure Determination
Source: Cambridge Crystallographic Data Centre
Synthesis and properties of oligo(biradicals) composed of 1,3-diphosphacyclobutane-2,4-diyl units and benzyl-type linkers
Source: Wiley
CCDC 958909: Experimental Crystal Structure Determination
Source: Cambridge Crystallographic Data Centre
Synthesis of a 1,3-diphosphacyclobutane-2,4-diyl from Mes*C[triple bond]P.
Source: (:unav)
Diradicals
Source: American Chemical Society (ACS)
Poly(biradicals): oligomers of 1,3-diphosphacyclobutane-2,4-diyl units.
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