GRAPHICAL ABSTRACT
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Abstract
The properties of 13 monodentate P-donor ligands not previously characterized in the Ligand Knowledge Base (LKB) approach have been determined computationally, allowing their addition to the LKB-P map of ligand space.Citation1 Consideration of ligand positions and close neighbors in ligand space can help to establish a chemical context and hence guide their application to organometallic catalysis. Here we demonstrate this potential application of the LKB-P map and discuss known and likely applications of these ligands.