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Phosphorus, Sulfur, and Silicon and the Related Elements Volume 190, 2015 - Issue 5-6: 20th International Conference on Phosphorus Chemistry (ICPC-2014)
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Original Articles

Reactions of 2-(2-Arylidenaminoaryloxy)Areno-1,3,2-Dioxaphosphole with Trifluoropyruvic and Mesoxalic Ethyl Esters. Synthesis of Cage Phosphoranes with the P–C and P–N Bonds

Mudaris DimukhametovA.E. Arbuzov Institute of Organic and Physical Chemistry, Russian Academy of Sciences, Kazan, 420088, Russia
,
Vladimir MironovA.E. Arbuzov Institute of Organic and Physical Chemistry, Russian Academy of Sciences, Kazan, 420088, Russia;Kazan Federal (Volga region) University, Kazan, 420008, RussiaCorrespondence[email protected]
,
Dmitry KrivolapovA.E. Arbuzov Institute of Organic and Physical Chemistry, Russian Academy of Sciences, Kazan, 420088, Russia
,
Ekaterina MironovaA.E. Arbuzov Institute of Organic and Physical Chemistry, Russian Academy of Sciences, Kazan, 420088, Russia
&
Islam AksunovKazan Federal (Volga region) University, Kazan, 420008, Russia
Pages 939-942 | Received 19 Aug 2014, Accepted 26 Nov 2014, Published online: 01 Jul 2015
 
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GRAPHICAL ABSTRACT

Abstract

Reaction of 2-(2-arylidenaminoaryloxy)areno-1,3,2-dioxaphosphole with trifluoropruvic and mesoxalic ethyl esters gives tricyclic cage phosphoranes with the P–C and Р–N bonds. The structure of one isolated diastereoisomer was established by XRD.

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Related Research Data

Tandem dihetero-Diels–Alder and Huisgen cycloaddition reactions. Synthesis, crystal structure and hydrolysis of the novel cage phosphoranes
Source: Royal Society of Chemistry (RSC)

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