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Phosphorus, Sulfur, and Silicon and the Related Elements Volume 190, 2015 - Issue 10
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Original Articles

First Donor-Stabilized Complexes of Manganese(II) with Disubstituted diphenyldithiophosphates: synthesis, characterization, biological, and X-ray Analysis

Mehak SajgotraDepartment of Chemistry, University of Jammu, Baba Saheb Ambedkar Road, Jammu, Jammu and Kashmir, 180006, India
,
Ruchi KhajuriaDepartment of Chemistry, University of Jammu, Baba Saheb Ambedkar Road, Jammu, Jammu and Kashmir, 180006, India
,
Sandeep KumarDepartment of Chemistry, University of Jammu, Baba Saheb Ambedkar Road, Jammu, Jammu and Kashmir, 180006, India
,
Atiya SyedDepartment of Chemistry, University of Jammu, Baba Saheb Ambedkar Road, Jammu, Jammu and Kashmir, 180006, India
,
Savit AndotraDepartment of Chemistry, University of Jammu, Baba Saheb Ambedkar Road, Jammu, Jammu and Kashmir, 180006, India
,
Gurvinder KourDepartment of Physics & Electronics, University of Jammu, Baba Saheb Ambedkar Road, Jammu, Jammu and Kashmir, 180006, India
,
Vivek K. GuptaDepartment of Physics & Electronics, University of Jammu, Baba Saheb Ambedkar Road, Jammu, Jammu and Kashmir, 180006, India
,
Rajni KantDepartment of Physics & Electronics, University of Jammu, Baba Saheb Ambedkar Road, Jammu, Jammu and Kashmir, 180006, India
&
Sushil K. PandeyDepartment of Chemistry, University of Jammu, Baba Saheb Ambedkar Road, Jammu, Jammu and Kashmir, 180006, IndiaCorrespondence[email protected]
 show all
Pages 1658-1667 | Received 20 Nov 2014, Accepted 22 Jan 2015, Published online: 02 Sep 2015
 
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GRAPHICAL ABSTRACT

Abstract

The complexes [{(ArO)2PS2}2Mn(NC5H5)2] (1–4) [(Ar = 2,4-(CH3)2C6H3 (1), 2,5-(CH3)2C6H3 (2), 3,4-(CH3)2C6H3 (3), and 3,5-(CH3)2C6H3) (4)] have been isolated in aqueous medium and characterized by mass spectrometer, IR, magnetic susceptibility, and single crystal X-ray analyses. The complex [{(2,4-(CH3)2C6H3O)2PS2)}2Mn(NC5H5)2] (1) crystallizes in the monoclinic space group P21/n as a monomer with a basic core of the

four-membered ring [MnS4]. The octahedral sphere of the Mn atom is completed by donation from the nitrogen atoms of the two pyridine rings and four sulfur atoms of the dithio moiety. The thermal gravimetric analysis of the complex (1) revealed the end product as MnS. Screening of the ligands and complexes against the fungus Fusarium oxysporum has indicated potential antifungal activity.

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