GRAPHICAL ABSTRACT
![](/cms/asset/0463e295-eefe-4e1e-9d14-dd6e59c81548/gpss_a_1036991_uf0001_b.gif)
Abstract
N-Sulfenylpyrroles were synthesized by the condensation of N-unsubstituted sulfenamides with 1,4-dicarbonyl compounds, such as hexane-2,5-dione or 2,5-dimethoxytetrahydrofuran. Primary amines as nucleophiles did not attack to the sulfur atom of the N-S bonds in the N-sulfenylpyrroles, which was different from other N-sulfenyl heterocycles.