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Phosphorus, Sulfur, and Silicon and the Related Elements Volume 191, 2016 - Issue 3: Reinhard Schmutzler Special Issue
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Original Articles

Pyrido-anellated 1,3-azaphospholes-current state and future challenges

Mohamed S. S. AdamInstitut für Biochemie (Anorganische Chemie), Ernst-Moritz-Arndt-Universität Greifswald, Greifswald, Germany
,
Mohammed GhalibInstitut für Biochemie (Anorganische Chemie), Ernst-Moritz-Arndt-Universität Greifswald, Greifswald, Germany
,
Gottfried J. PalmInstitut für Biochemie (Molekulare Strukturbiologie), Ernst-Moritz-Arndt-Universität Greifswald, Greifswald, Germany
,
Peter G. JonesInstitut für Anorganische und Analytische Chemie, Technische Universität Braunschweig, Braunschweig, Germany
&
Joachim W. HeinickeInstitut für Biochemie (Anorganische Chemie), Ernst-Moritz-Arndt-Universität Greifswald, Greifswald, GermanyCorrespondence[email protected]
Pages 548-557 | Received 09 Sep 2015, Accepted 07 Oct 2015, Published online: 17 Mar 2016
 
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GRAPHICAL ABSTRACT

ABSTRACT

A short overview of the syntheses, properties and some reactions of pyrido-anellated 1.3-azaphospholes is presented. Except for 2-phosphaindolizines, which have been intensively studied with respect to syntheses, electrophilic substitution and cycloadditions, this is a class of compound that has still been only sparingly investigated. Preliminary results and hints as to possible perspectives are included to encourage further research on these novel P,N hybrid ligands.

Acknowledgments

We thank Dr. M. K. Kindermann, G. Thede and M. Steinich for numerous NMR spectra, Prof. Dr. H.-C. Böttcher and B. Breitenstein (Department Chemie, Ludwig-Maximilians-Universität München) for HRMS (DEI) and Dr. H. Frauendorf and G. Sommer-Udvarnoki (Georg-August-Universität Göttingen, Institut für Organische und Biomolekulare Chemie) for HRMS (ESI) measurements, performed within our contributions to this research.

Funding

A scholarship to M.S.S.A. by the Deutsche Akademische Auslandsdienst (DAAD) and financial support of the investigations on pyridoazaphospholes within a project on anellated 1H-1,3-azaphospholes is kindly acknowledged.

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