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Phosphorus, Sulfur, and Silicon and the Related Elements Volume 191, 2016 - Issue 6
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Original Articles

N-isocyaniminotriphenylphosphorane (Ph3PNNC) as an efficient reagent for the synthesis of ferrocene-containing 1,3,4-oxadiazole derivatives

Ali RamazaniDepartment of Chemistry, University of Zanjan, Zanjan, IranCorrespondence[email protected]
,
Nadia FattahiDepartment of Chemistry, University of Zanjan, Zanjan, Iran
,
Mona AshtariDepartment of Chemistry, University of Zanjan, Zanjan, Iran
,
Aram RezaeiDepartment of Chemistry, University of Zanjan, Zanjan, Iran
&
Sang Woo JooSchool of Mechanical Engineering, Yeungnam University, Gyeongsan, Republic of KoreaCorrespondence[email protected]
Pages 908-912 | Received 12 Aug 2015, Accepted 28 Oct 2015, Published online: 28 Apr 2016
 
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GRAPHICAL ABSTRACT

ABSTRACT

Reaction of N-isocyaniminotriphenylphosphorane (Ph3PNNC) with an aromatic aldehyde in the presence of ferrocene carboxylic acid and a secondary amine proceeds smoothly at room temperature under neutral conditions to afford sterically congested ferrocene-containing 1,3,4-oxadiazole derivatives in high yields. The reaction progresses smoothly and clearly under mild conditions and no side reactions were observed.

Funding

This work is funded by 2015 Yeungnam University Research Grant.

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Related Research Data

Synthesis and X-ray single crystal structure analysis of a new 2-chlorobenzyl ammonium salt of phosphonic acid
Source: Informa UK Limited
N-isocyaniminotriphenylphosphorane (Ph3PNNC) as an efficient reagent for the synthesis of ferrocene-containing 1,3,4-oxadiazole derivatives
Source: figshare Academic Research System
N-isocyaniminotriphenylphosphorane (Ph3PNNC) as an efficient reagent for the synthesis of ferrocene-containing 1,3,4-oxadiazole derivatives
Source: Figshare
N-isocyaniminotriphenylphosphorane (Ph3PNNC) as an efficient reagent for the synthesis of ferrocene-containing 1,3,4-oxadiazole derivatives
Source: Figshare

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