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Phosphorus, Sulfur, and Silicon and the Related Elements Volume 191, 2016 - Issue 11-12: 21st International Conference on Phosphorus Chemistry (ICPC-2016)
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Original Articles

The formation of secondary arylphosphines in the reaction of organonickel sigma-complex [NiBr(Mes)(bpy)], where Mes = 2,4,6-trimethylphenyl, bpy = 2,2′-bipyridine, with phenylphosphine

Zufar N. GafurovA.E. Arbuzov Institute of Organic and Physical Chemistry, Kazan Scientific Center, Russian Academy of Sciences, Kazan, Russian Federation;Kazan Federal University, Kazan, Russian Federation
,
Lenar I. MusinA.E. Arbuzov Institute of Organic and Physical Chemistry, Kazan Scientific Center, Russian Academy of Sciences, Kazan, Russian Federation
,
Il'yas F. SakhapovA.E. Arbuzov Institute of Organic and Physical Chemistry, Kazan Scientific Center, Russian Academy of Sciences, Kazan, Russian Federation;Kazan Federal University, Kazan, Russian Federation
,
Vasily M. BabaevA.E. Arbuzov Institute of Organic and Physical Chemistry, Kazan Scientific Center, Russian Academy of Sciences, Kazan, Russian Federation
,
Elvira I. MusinaA.E. Arbuzov Institute of Organic and Physical Chemistry, Kazan Scientific Center, Russian Academy of Sciences, Kazan, Russian Federation
,
Andrey A. KarasikA.E. Arbuzov Institute of Organic and Physical Chemistry, Kazan Scientific Center, Russian Academy of Sciences, Kazan, Russian Federation
,
Oleg G. SinyashinA.E. Arbuzov Institute of Organic and Physical Chemistry, Kazan Scientific Center, Russian Academy of Sciences, Kazan, Russian Federation
&
Dmitry G. YakhvarovA.E. Arbuzov Institute of Organic and Physical Chemistry, Kazan Scientific Center, Russian Academy of Sciences, Kazan, Russian Federation;Kazan Federal University, Kazan, Russian FederationCorrespondence[email protected]
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Pages 1475-1477 | Received 08 Jul 2016, Accepted 08 Jul 2016, Published online: 25 Jul 2016
 
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GRAPHICAL ABSTRACT

ABSTRACT

The reactivity of organonickel sigma-complex [NiBr(Mes)(bpy)], where Mes = 2,4,6-trimethylphenyl, bpy = 2,2′-bipyridine towards phenylphosphine (PhPH2) has been investigated. It was found that this interaction leads to secondary mesitylphenylphosphine and dimesitylphosphine by formation of new carbon-phosphorus bond involving mesityl fragment of starting organonickel sigma-complex.

Funding

This work is financially supported by the Russian Science Foundation (project 14-13-01122).

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Related Research Data

Classification and synthesis of nickel pincer complexes
Source: Springer Science and Business Media LLC
New 2,2'-bipyridine and 1,10-phenanthroline based nickel(II) phosphates
Source: Informa UK Limited

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