Thermal stability of primary and secondary phosphine oxides formed as a reaction of phosphine oxide with ketones

E. V. GorbachukA.E. Arbuzov Institute of Organic and Physical Chemistry, Kazan Scientific Center of the Russian Academy of Sciences, Kazan, Russian Federation;A.M. Butlerov Institute of Chemistry, Kazan Federal University, Kazan, Russian Federation

E. K. BadeevaA.E. Arbuzov Institute of Organic and Physical Chemistry, Kazan Scientific Center of the Russian Academy of Sciences, Kazan, Russian Federation

S. A. KatsyubaA.E. Arbuzov Institute of Organic and Physical Chemistry, Kazan Scientific Center of the Russian Academy of Sciences, Kazan, Russian Federation

P. O. PavlovA.E. Arbuzov Institute of Organic and Physical Chemistry, Kazan Scientific Center of the Russian Academy of Sciences, Kazan, Russian Federation;A.M. Butlerov Institute of Chemistry, Kazan Federal University, Kazan, Russian Federation

Kh. R. KhayarovA.M. Butlerov Institute of Chemistry, Kazan Federal University, Kazan, Russian Federation

O. G. SinyashinA.E. Arbuzov Institute of Organic and Physical Chemistry, Kazan Scientific Center of the Russian Academy of Sciences, Kazan, Russian Federation

D. G. YakhvarovA.E. Arbuzov Institute of Organic and Physical Chemistry, Kazan Scientific Center of the Russian Academy of Sciences, Kazan, Russian Federation;A.M. Butlerov Institute of Chemistry, Kazan Federal University, Kazan, Russian FederationCorrespondence[email protected]

show all

GRAPHICAL ABSTRACT

ABSTRACT

We present the study of reactivity of electrochemically generated in situ from white phosphorus P₄ phosphine oxide H₃PO toward various ketones (acetone, methylethylketone, methyl-n-propylketone). This interaction was found to give a selective formation of mono- and bis-(α-oxyalkyl)phosphine oxides RR′C(OH)P(O)H₂ (1) and (RR′C(OH))₂P(O)H (2) where R = Me; R′ = Me, Et, n-Pr. Thermal properties of the formed primary and secondary phosphine oxides have been studied and quantum chemical calculations of thermodynamic stability of these compounds were performed.

KEYWORDS:

Funding

This work is financially supported by the Russian Science Foundation (project 14-13-01122).

Reprints and Corporate Permissions

Please note: Selecting permissions does not provide access to the full text of the article, please see our help page How do I view content?

To request a reprint or corporate permissions for this article, please click on the relevant link below:

Order Reprints Request Corporate Permissions

Academic Permissions

Please note: Selecting permissions does not provide access to the full text of the article, please see our help page How do I view content?

Obtain permissions instantly via Rightslink by clicking on the button below:

Request Academic Permissions

If you are unable to obtain permissions via Rightslink, please complete and submit this Permissions form. For more information, please visit our Permissions help page.

Thermal stability of primary and secondary phosphine oxides formed as a reaction of phosphine oxide with ketones

Related Research Data

Information for

Open access

Opportunities

Help and information

Thermal stability of primary and secondary phosphine oxides formed as a reaction of phosphine oxide with ketones

GRAPHICAL ABSTRACT

ABSTRACT

Funding

Reprints and Corporate Permissions

Academic Permissions

Related Research Data

Related research

To cite this article:

Download citation

Information for

Open access

Opportunities

Help and information

Keep up to date

Your download is now in progress and you may close this window

Login or register to access this feature