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Phosphorus, Sulfur, and Silicon and the Related Elements Volume 191, 2016 - Issue 11-12: 21st International Conference on Phosphorus Chemistry (ICPC-2016)
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Original Articles

New catalysts for PEM fuel cells

M. K. KadirovA.E. Arbuzov Institute of Organic and Physical Chemistry, Kazan Scientific Center, Russian Academy of Sciences, Kazan, Russia;Kazan National Research Technological University, Kazan, RussiaCorrespondence[email protected]
,
T. I. IsmaevKazan National Research Technological University, Kazan, Russia
,
R. A. SafiullinKazan National Research Technological University, Kazan, Russia
,
I. R. NizameevA.E. Arbuzov Institute of Organic and Physical Chemistry, Kazan Scientific Center, Russian Academy of Sciences, Kazan, Russia
,
I. D. StrelnikA.E. Arbuzov Institute of Organic and Physical Chemistry, Kazan Scientific Center, Russian Academy of Sciences, Kazan, Russia
,
E. I. MusinaA.E. Arbuzov Institute of Organic and Physical Chemistry, Kazan Scientific Center, Russian Academy of Sciences, Kazan, Russia
,
Yu. H. BudnikovaA.E. Arbuzov Institute of Organic and Physical Chemistry, Kazan Scientific Center, Russian Academy of Sciences, Kazan, Russia
,
A. A. KarasikA.E. Arbuzov Institute of Organic and Physical Chemistry, Kazan Scientific Center, Russian Academy of Sciences, Kazan, Russia
&
O. G. SinyashinA.E. Arbuzov Institute of Organic and Physical Chemistry, Kazan Scientific Center, Russian Academy of Sciences, Kazan, Russia
 show all
Pages 1488-1490 | Received 08 Jul 2016, Accepted 08 Jul 2016, Published online: 25 Jul 2016
 
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GRAPHICAL ABSTRACT

ABSTRACT

Fuel cell (FC) test results have been obtained for the first time with the bis-ligand nickel(ii) complex of 1,4-diaza-3,7-diphosphacyclootane heterogeneous catalyst. Using AFM technique the [Ni(PPh2Np-Tol2)2](BF4)2 self-assemblies morphology on pyrolytic graphite has been studied. By the method of rotating disk electrode the mechanism of FC cathode side reaction has been investigated

Funding

This research was supported by the Russian Foundation for Basic Researches (grant no.14-03-00258A) and by a Program of the Presidium of Russian Academy of Sciences.

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Related Research Data

1,5‐Diaza‐3,7‐Diphosphacyclooctane Bis‐Ligand Nickel(II) Complexes as Oxygen Reduction Catalysts for Proton‐Exchange Membrane Fuel Cells
Source: Wiley

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