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Phosphorus, Sulfur, and Silicon and the Related Elements Volume 191, 2016 - Issue 11-12: 21st International Conference on Phosphorus Chemistry (ICPC-2016)
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Original Articles

Luminescent copper(I) and gold(I) complexes of 1,5-diaza-3,7-diphosphacyclooctanes

I. StrelnikA.E. Arbuzov Institute of Organic and Physical Chemistry, Kazan, Russia;Institute of Chemistry, Saint-Petersburg State University, Saint-Petersburg, RussiaCorrespondence[email protected]
,
E. MusinaA.E. Arbuzov Institute of Organic and Physical Chemistry, Kazan, Russia
,
E. GrachovaInstitute of Chemistry, Saint-Petersburg State University, Saint-Petersburg, Russia
,
A. KarasikA.E. Arbuzov Institute of Organic and Physical Chemistry, Kazan, Russia
&
O. SinyashinA.E. Arbuzov Institute of Organic and Physical Chemistry, Kazan, Russia
Pages 1518-1519 | Received 10 Jul 2016, Accepted 10 Jul 2016, Published online: 27 Jul 2016
 
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GRAPHICAL ABSTRACT

ABSTRACT

The pyridyl substituted 1,5-diaza-3,7-diphosphacyclooctanes were utilized for the luminescent copper(I) and gold(I) complexes design. The structures of the obtained metal complexes depend on the metal ion origin, availability of the pyridyl group for coordination, and coligands coordination ability. All the presented complexes demonstrate emission from blue to orange range of spectra. It was found the rare white emission of the hexanuclear copper(I) complexes. Dinuclear gold(I) complexes display a luminescent vapochromism and thermochroism. The tuning of that luminescent phenomenon is possible by variation of the substituents.

Funding

The work is supported by the RSF research grant 15-13-30031.

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