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Original Articles

Substituent effects in the asymmetric Diels-Alder cycloaddition of 3,4,5-triaryl-1-(+)-neomenthyl-1,2-diphospholes’ with maleic acid derivatives

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Pages 1530-1532 | Received 10 Jul 2016, Accepted 10 Jul 2016, Published online: 28 Jul 2016
 

GRAPHICAL ABSTRACT

ABSTRACT

Asymmetric phospha-Diels-Alder reactions involving new 3,4,5-triaryl-1-(+)-neomenthyl-1,2-diphosphole bearing a chiral auxiliary with maleic acid derivatives with diastereoselectivities up to 91% are described.

Funding

This work was supported by the Russian Science Foundation (project no. 14-13-00589).

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