ABSTRACT
Organophosphorus compounds containing the P-C-N moiety have been synthesized by microwave-assisted condensations. The synthesis of chiral α-aminophosphonate and α-aminophosphinate derivatives was studied using etyl octyl phosphite or alkyl phenyl-H-phosphinates. Amino-methylenebisphosphonates and amino-methylenebisphosphine oxides were also prepared by the three-component condensation of an amine, an orthoformate and the appropriate >P(O)H reagent.
Funding
The above project was supported by the Hungarian Scientific Research Fund (PD111895) and the Hungarian Research Development and Innovation Fund (K119202). Ádám Tajti is grateful for the financial support from the Gedeon Richter Talentum Foundation.