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Phosphorus, Sulfur, and Silicon and the Related Elements Volume 191, 2016 - Issue 11-12: 21st International Conference on Phosphorus Chemistry (ICPC-2016)
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Original Articles

Direct phosphorylation of pyridine in the presence of Ni(BF4)2bpy and CoCl2bpy metal complexes

S. O. StrekalovaA.E. Arbuzov Institute of Organic and Physical Chemistry, Kazan Scientific Center, Russian Academy of Sciences, Kazan, RussiaCorrespondence[email protected]
,
M. N. KhrizanforovA.E. Arbuzov Institute of Organic and Physical Chemistry, Kazan Scientific Center, Russian Academy of Sciences, Kazan, Russia
,
A. V. ShamsievaA.E. Arbuzov Institute of Organic and Physical Chemistry, Kazan Scientific Center, Russian Academy of Sciences, Kazan, Russia
,
V. V. GrinenkoA.E. Arbuzov Institute of Organic and Physical Chemistry, Kazan Scientific Center, Russian Academy of Sciences, Kazan, Russia
,
T. V. GryaznovaA.E. Arbuzov Institute of Organic and Physical Chemistry, Kazan Scientific Center, Russian Academy of Sciences, Kazan, Russia
,
E. I. MusinaA.E. Arbuzov Institute of Organic and Physical Chemistry, Kazan Scientific Center, Russian Academy of Sciences, Kazan, Russia
,
A. A. KarasikA.E. Arbuzov Institute of Organic and Physical Chemistry, Kazan Scientific Center, Russian Academy of Sciences, Kazan, Russia
&
Y. H. BudnikovaA.E. Arbuzov Institute of Organic and Physical Chemistry, Kazan Scientific Center, Russian Academy of Sciences, Kazan, Russia
 show all
Pages 1545-1546 | Received 12 Jul 2016, Accepted 12 Jul 2016, Published online: 02 Aug 2016
 
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GRAPHICAL ABSTRACT

ABSTRACT

A new approach to the phosphorylation of pyridine with diethyl-H-phosphonate in the presence of metal complexes Ni(BF4)2bpy and CoCl2bpy is described. The reaction is carried out in electrochemical mild conditions (room temperature, normal pressure) and the ratio of the reagents is 1: 1. This method forms a pyridylphosphonate with high yield (up to 90%) and 100% conversion of H-phosphonate.

Funding

This work was supported by the Russian Science Foundation No. 14-23-00016.

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Related Research Data

Evaluation of Transition Metal Catalysts in Electrochemically Induced Aromatic Phosphonation.
Source: MDPI AG
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