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Original Articles

Tetracarbonyltungsten (0) and –molybdenum (0) complexes of P,N-containing cyclophanes

, , , &
Pages 1581-1582 | Received 20 Jul 2016, Accepted 20 Jul 2016, Published online: 05 Aug 2016
 

GRAPHICAL ABSTRACT

ABSTRACT

The interaction of P,N-containing cyclophanes containing two 1,5-diaza-3,7-diphosphacyclooctane fragments with tetracarbonyl(tetrahydrofuran)tungnsten(0) or tetracarbonyl(norbornadiene)molybdenum(0) leads to binuclear bis-P,P-chelate complexes with tetracarbonylmetal moieties located outside of the macrocyclic cavities; the complexation is sensitive to ligands structures and bulky substituents on phosphorus atoms prevent the complexation of VI group metals.

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