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Original Articles

Reduction of phosphine oxides under green chemical conditions

, , , &
Pages 1597-1598 | Received 20 Jul 2016, Accepted 20 Jul 2016, Published online: 11 Aug 2016
 

GRAPHICAL ABSTRACT

ABSTRACT

The deoxygenation of phosphine oxides was studied on a series of model reactions using an aralkylsilane, arylsilanes, diarylsilanes, a disiloxane, a polysiloxane, and a disilane under solvent-free, thermal, or microwave-assisted conditions. The deoxygenations were optimized, and the reactivity of the silanes was evaluated. User-friendly accomplishments were elaborated.

Funding

This project was supported by the Hungarian Research Development and Innovation Fund (K119202). T. Kovács is grateful for the fellowship provided by Chinoin-Sanofi.

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