Octathiotetraphosphetanes—Novel class of biologically active phosphorusorganic compounds: Synthesis, structure, properties

E. S. BatyevaA. E. Arbuzov Institute of Organic and Physical Chemistry, Kazan Scientific Centre of the Russian Academy of Sciences, Kazan, Russian Federation

E. K. BadeevaA. E. Arbuzov Institute of Organic and Physical Chemistry, Kazan Scientific Centre of the Russian Academy of Sciences, Kazan, Russian FederationCorrespondence[email protected]

O. G. SinyashinA. E. Arbuzov Institute of Organic and Physical Chemistry, Kazan Scientific Centre of the Russian Academy of Sciences, Kazan, Russian Federation

I. S. NizamovA. E. Arbuzov Institute of Organic and Physical Chemistry, Kazan Scientific Centre of the Russian Academy of Sciences, Kazan, Russian Federation

L. V. FrolovaBiology Department, Chemistry Department, New Mexico Institute of Mining and Technology, Socorro, NM, USA

S. RogeljBiology Department, Chemistry Department, New Mexico Institute of Mining and Technology, Socorro, NM, USA

L. I. KurchevaA. E. Arbuzov Institute of Organic and Physical Chemistry, Kazan Scientific Centre of the Russian Academy of Sciences, Kazan, Russian Federation

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GRAPHICAL ABSTRACT

ABSTRACT

Reaction of white phosphorus with elemental sulfur and proton-donating reagents such as thiols and diols in the presence of different amines were studied. Octathiotetraphosphetane ammonium salts, ammonium salts of S,S′-dialkyltetratiophosphoric and O,O′-propylendithiophosphoric acids were obtained from the reactions. Red phosphorus reacted with sulfur and amines in the presence of microwave irradiation to form ammonium octathiotetraphosphetanes in high yields.

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Funding

The study was performed with the financial support of the Russian Foundation for Basic Researches (Grant No. 15-03-01394-a).

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Octathiotetraphosphetanes—Novel class of biologically active phosphorusorganic compounds: Synthesis, structure, properties

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Octathiotetraphosphetanes—Novel class of biologically active phosphorusorganic compounds: Synthesis, structure, properties

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