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Phosphorus, Sulfur, and Silicon and the Related Elements Volume 191, 2016 - Issue 11-12: 21st International Conference on Phosphorus Chemistry (ICPC-2016)
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Original Articles

Electrochemical oxidative phosphonation of azoles

T. V. GryaznovaA.E. Arbuzov Institute of Organic and Physical Chemistry, Kazan Scientific Center of Russian Academy of Sciences, Kazan, Russian FederationCorrespondence[email protected]
,
M. N. KhrizanforovA.E. Arbuzov Institute of Organic and Physical Chemistry, Kazan Scientific Center of Russian Academy of Sciences, Kazan, Russian Federation
,
S. O. StrekalovaA.E. Arbuzov Institute of Organic and Physical Chemistry, Kazan Scientific Center of Russian Academy of Sciences, Kazan, Russian Federation
,
Y. H. BudnikovaA.E. Arbuzov Institute of Organic and Physical Chemistry, Kazan Scientific Center of Russian Academy of Sciences, Kazan, Russian Federation
&
O. G. SinyshinA.E. Arbuzov Institute of Organic and Physical Chemistry, Kazan Scientific Center of Russian Academy of Sciences, Kazan, Russian Federation
Pages 1658-1659 | Received 12 Aug 2016, Accepted 12 Aug 2016, Published online: 23 Aug 2016
 
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GRAPHICAL ABSTRACT

ABSTRACT

Metal-catalyzed electrochemical oxidative phosphonation of hetaryl-azoles (benzoxazoles, benzothiazole and others) with dialkyl-H-phosphonate was developed. Joint electrochemical oxidation of azoles and dialkyl-H-phosphonate mixtures in the presence of catalytic quantities of salts of transition metals at room temperature affords the desired 2-substituted azoles. Palladium, nickel and silver salts were tested as catalysts.

Funding

This work was supported by the Russian Science Foundation (grant no. 14-23-00016).

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