Electrooxidative phosphorylation of coumarins by bimetallic catalytic systems Ni(II)/Mn(II) or Co(II)/Mn(II)

V. V. GrinenkoA.E. Arbuzov Institute of Organic and Physical Chemistry, Kazan Scientific Center, Russian Academy of Sciences, Kazan, RussiaCorrespondence[email protected]

M. N. KhrizanforovA.E. Arbuzov Institute of Organic and Physical Chemistry, Kazan Scientific Center, Russian Academy of Sciences, Kazan, Russia

S. O. StrekalovaA.E. Arbuzov Institute of Organic and Physical Chemistry, Kazan Scientific Center, Russian Academy of Sciences, Kazan, Russia

V. V. KhrizanforovaA.E. Arbuzov Institute of Organic and Physical Chemistry, Kazan Scientific Center, Russian Academy of Sciences, Kazan, Russia

K. V. KholinA.E. Arbuzov Institute of Organic and Physical Chemistry, Kazan Scientific Center, Russian Academy of Sciences, Kazan, Russia

T. V. GryaznovaA.E. Arbuzov Institute of Organic and Physical Chemistry, Kazan Scientific Center, Russian Academy of Sciences, Kazan, Russia

Y. H. BudnikovaA.E. Arbuzov Institute of Organic and Physical Chemistry, Kazan Scientific Center, Russian Academy of Sciences, Kazan, Russia

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GRAPHICAL ABSTRACT

ABSTRACT

The phosphorylation of coumarins (coumarin, 6-methylcoumarin, 7-methylcoumarin) by catalytic oxidation of a mixture of coumarins and diethyl phosphite (1:1) in electrochemical mild conditions (room temperature and normal pressure) using bimetallic catalyst systems, MnCl₂bpy/Ni(BF₄)₂bpy or MnCl₂bpy/CoCl₂bpy(bpy-2,2′-bipyridine) was realized.

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Funding

This work was supported by the grant of the Russia Science Foundation No. 14-23-00016.

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Electrooxidative phosphorylation of coumarins by bimetallic catalytic systems Ni(II)/Mn(II) or Co(II)/Mn(II)

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Electrooxidative phosphorylation of coumarins by bimetallic catalytic systems Ni(II)/Mn(II) or Co(II)/Mn(II)

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