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Phosphorus, Sulfur, and Silicon and the Related Elements Volume 192, 2017 - Issue 3
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Original Articles

Triphenylphosphine-supported synthesis of two-dimensional silver(I) complex with (1,3,4-thiadiazole-2,5-diyldithio)diacetic acid

Noor H. A. SubriSchool of Chemical Sciences, Universiti Sains Malaysia, Penang, Malaysia
,
Umie F. M. HazizSchool of Chemical Sciences, Universiti Sains Malaysia, Penang, Malaysia
&
Mohd. R. RazaliSchool of Chemical Sciences, Universiti Sains Malaysia, Penang, MalaysiaCorrespondence[email protected]
Pages 271-275 | Received 01 Aug 2016, Accepted 09 Sep 2016, Published online: 16 Nov 2016
 
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GRAPHICAL ABSTRACT

ABSTRACT

The reaction of dicarboxylate ligand, (1,3,4-thiadiazole-2,5-diyldithio)diacetic acid (H2tdza) with silver(I) acetate and triphenylphosphine (PPh3) facilitate the formation of complex [Ag2(tdza)(PPh3)2]n (1). The complex was characterized by elemental analysis, FT-IR spectroscopy, 1H-NMR, 13C-NMR and 31P-NMR spectroscopy, and single crystal X-ray diffraction. Structural analysis revealed that complex 1 has a 2D topologically promising architecture as a result from the formation of 26-membered cyclic ring. The tdza2− ligand in 1 displays unprecedented µ4-bridging mode which is also the first example for this ligand. The interdigitating arrangement and π-π stacking between 2D arrays stabilized the formation of complex 1.

Funding

This work was supported by RUI grant 1001/PKIMIA/811260.

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