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Phosphorus, Sulfur, and Silicon and the Related Elements Volume 192, 2017 - Issue 3
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Original Articles

1,1,2,2-Tetrahydroperoxy-1,2-diphenylethane as new oxidant for chemoselective and catalyst free oxidation of sulfides to sulfoxides and sulfones

Kaveh KhosraviDepartment of Chemistry, Faculty of Science, Arak University, Arak, IranCorrespondence[email protected]
,
Shirin NaserifarDepartment of Chemistry, Faculty of Science, Arak University, Arak, Iran
,
Boshra MahmoudiChemical Engineering Department, Faculty of Engineering, Soran University, Erbil/Soran, Iraq-Kurdistan Region
&
Kobra KhalajiDepartment of Chemistry, Faculty of Science, Arak University, Arak, Iran
Pages 316-321 | Received 14 Jul 2016, Accepted 14 Sep 2016, Published online: 27 Dec 2016
 
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GRAPHICAL ABSTRACT

ABSTRACT

A catalyst free and chemoselective oxidation of sulfides to sulfoxides or sulfones was developed using 1,1,2,2-tetrahydroperoxy-1,2-diphenylethane as a new oxidant. This scope has shown the achievement of various sulfoxides and sulfones which were obtained selectively in high yields at room temperature.

Funding

Financial support from Arak University is gratefully acknowledged.

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