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Phosphorus, Sulfur, and Silicon and the Related Elements Volume 192, 2017 - Issue 3
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Original Articles

Bi(NO3)3.5H2O catalyzed phosphonylation of aldehydes: An efficient route to α-hydroxyphosphonates

Anil KumarSynthetic Organic Chemistry Lab., Faculty of Sciences, Shri Mata Vaishno Devi University, Katra, Jammu & Kashmir, IndiaCorrespondence[email protected]
,
Shivali JamwalSynthetic Organic Chemistry Lab., Faculty of Sciences, Shri Mata Vaishno Devi University, Katra, Jammu & Kashmir, India
,
Shahaba KhanSynthetic Organic Chemistry Lab., Faculty of Sciences, Shri Mata Vaishno Devi University, Katra, Jammu & Kashmir, India
,
Nasseb SinghSynthetic Organic Chemistry Lab., Faculty of Sciences, Shri Mata Vaishno Devi University, Katra, Jammu & Kashmir, India
&
Vijai K. RaiDepartment of Chemistry, Guru Ghasidas Vishwavidyalaya, Bilaspur, Chhattisgarh, India
Pages 381-385 | Received 01 Feb 2016, Accepted 07 Oct 2016, Published online: 04 Jan 2017
 
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GRAPHICAL ABSTRACT

ABSTRACT

The Bi(NO3)3.5H2O mediated synthesis of α-hydroxyphosphonates via phosphonylation of aldehydes is reported herein. Both conventional and microwave technology was efficiently applied to range of aromatic, heteroaromatic, α,β-unsaturated aldehydes under solvent-free conditions. The solvent free conditions, avoidance of toxic reagents and excellent yield are some of the remarkable features of this protocol to access the medicinally privileged structure, α-hydroxyphosphonates.

Acknowledgment

We are thankful to IIIM Jammu for providing spectra.

Funding

We sincerely thank UGC, New Delhi for its financial support [F. No. 39-788/2010 (SR)].

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