New functionalized organophosphorus derivatives of methane- and ethanesulfonic acids with P-C-N moieties

GRAPHICAL ABSTRACT

ABSTRACT

Convenient methods of syntheses of new organophosphorus alkanesulfonylamides from the trivalent organophosphorus acid esters and reactive N-methyl N-chloromethyl methanesulfonylamide, phosphorylated methylamines with NH- and NSi moieties, trimethylsilyl vinylsulfonate, and N,N-diethylvinylsulfonamide were developed. The new types of functionalized organophosphorus derivatives of methane- and ethanesulfonic acids with P-C-N moieties were afforded in good yields.

KEYWORDS:

• Trivalent phosphorus acid esters
• N-methyl N-chloromethylmethanesulfonylamide
• trimethylsilyl vinylsulfonate
• N,N-diethylvinylsulfonamide
• organophosphorus alkanesulfonylamides

Funding

This work was financially supported by the Russian Foundation for Basic Research (grant numbers 14-03-00001, 15-03-00002 and 17-03-00169).