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Phosphorus, Sulfur, and Silicon and the Related Elements Volume 192, 2017 - Issue 6: Harry Hudson Special Issue
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Original Articles

A new macrocyclic [FeFe]-hydrogenase H cluster model

Hassan Abul-FutouhInstitut für Anorganische und Analytische Chemie, Friedrich-Schiller-Universität Jena, Jena, Germany
,
Helmar GörlsInstitut für Anorganische und Analytische Chemie, Friedrich-Schiller-Universität Jena, Jena, Germany
&
Wolfgang WeigandInstitut für Anorganische und Analytische Chemie, Friedrich-Schiller-Universität Jena, Jena, GermanyCorrespondence[email protected]
Pages 634-637 | Received 12 Dec 2016, Accepted 17 Jan 2017, Published online: 25 May 2017
 
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GRAPHICAL ABSTRACT

ABSTRACT

A novel macrocyclic complex [Fe2(CO)6{µ-(S(CH2)3)2S}]2 (2) has been synthesized by the reaction of Fe3(CO)12 with 1,2,6,10,11,15-hexathiacyclooctadecane (1). This tetranuclear macrocyclic complex has been isolated and characterized by IR spectroscopy, 1H NMR spectroscopy, mass spectrometry as well as elemental analysis. The solid state structures of 1,2,6,10,11,15-hexathiacyclooctadecane (1) and [Fe2(CO)6{µ-(S(CH2)3)2S}]2 (2) were determined by X-ray crystal structure analysis.

Funding

H. Abul-Futouh thanks the Deutscher Akademischer Austansch Dienst (DAAD) for scholarship.

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