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Phosphorus, Sulfur, and Silicon and the Related Elements Volume 192, 2017 - Issue 6: Harry Hudson Special Issue
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Original Articles

Reaction of allenylphosphonates/allenylphosphine oxides with thiocyanates/isothiocyanates or oxalyl chloride/AgNO3

K. C. Kumara SwamySchool of Chemistry, University of Hyderabad, Hyderabad, Telangana, IndiaCorrespondence[email protected]
,
Manab ChakravartySchool of Chemistry, University of Hyderabad, Hyderabad, Telangana, India;Department of Chemistry, Birla Institute of Technology & Science, Pilani Hyderabad Campus, Jawahar Nagar, Shameerpet Mandal, Hyderabad, Telangana, India
,
Shubham DebnathSchool of Chemistry, University of Hyderabad, Hyderabad, Telangana, India
&
M. Nagarjuna ReddySchool of Chemistry, University of Hyderabad, Hyderabad, Telangana, India
Pages 763-768 | Received 30 Dec 2016, Accepted 24 Jan 2017, Published online: 25 May 2017
 
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GRAPHICAL ABSTRACT

ABSTRACT

In this paper, we describe thiocyanation as well as chlorination of selected allenylphosphonates/allenyl phosphine oxide, using ammonium thiocaynate or (OCH2CMe2CH2O)PNCS (for thiocyanation) or oxalyl chloride/AgNO3 for chlorination. The resulting products are vinyl (thiocyanato)phosphonates or vicinal dichloro(vinyl) phosphonates. One of the vinyl thiocyanato-phosphonates is characterized by single crystal X-ray crystallography.

Funding

We thank the Council of Scientific and Industrial Research (CSIR), Department of Science and Technology (DST-FIST and PURSE), and University Grants Commission (UGC-UPE-2) for financial support.

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