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Phosphorus, Sulfur, and Silicon and the Related Elements Volume 193, 2018 - Issue 1
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Original Articles

Chemistry of phosphorus ylides: Part 45 synthesis of phosphoranylidene, thietane, azetidine and thiazinane derivatives as potent chemo preventative agents

Ahmed I. HashemChemistry Department, Faculty of Science, Ain Shams University, Abassia, Cairo, Egypt
,
Marwa El-HussienyDepartment of Organometallic and Organometalloid Chemistry, National Research Centre, Dokki, Giza, EgyptORCID Iconhttp://orcid.org/0000-0002-5491-0750
ORCID Icon,
Mansoura A. Abd-El-MaksoudDepartment of Organometallic and Organometalloid Chemistry, National Research Centre, Dokki, Giza, Egypt
,
Soher S. MaigaliDepartment of Organometallic and Organometalloid Chemistry, National Research Centre, Dokki, Giza, Egypt
,
Shaimaa T. MansourDepartment of Organometallic and Organometalloid Chemistry, National Research Centre, Dokki, Giza, Egypt
&
Fouad M. SolimanDepartment of Organometallic and Organometalloid Chemistry, National Research Centre, Dokki, Giza, EgyptCorrespondence[email protected]
Pages 1-9 | Received 07 Mar 2017, Accepted 16 Jul 2017, Published online: 18 Sep 2017
 
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GRAPHICAL ABSTRACT

ABSTRACT

Reactions of nucleophilic active phosphacumulenes with iso(thio)cyanate compounds were performed. The reaction products depend on the nature of the reagent, substrate and the condition of the reaction used. New heterocyclic 4-membered or 6-membered sulfur and nitrogen compounds such as phosphoranylidene thietane, azetidine and thiazinane were obtained. On the other hand, the stable phosphonium ylides with the iso(thio)cyanate afforded phosphoranylidene thiocarbamoyl derivatives. Possible reaction mechanisms are considered and the structural assignments are based on compatible analytical and spectroscopic data.

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Related Research Data

Chemistry of Phosphorus Ylides: Part 45 Synthesis of Phosphoranylidene Thietane, Azetidine and Thiazinane Derivatives as Potent Chemo Preventative Agents
Source: Figshare
Chemistry of phosphorus ylides: Part 45 synthesis of phosphoranylidene, thietane, azetidine and thiazinane derivatives as potent chemo preventative agents
Source: Figshare
CCDC 1532652: Experimental Crystal Structure Determination
Source: Cambridge Crystallographic Data Centre
Chemistry of phosphorus ylides: Part 45 synthesis of phosphoranylidene, thietane, azetidine and thiazinane derivatives as potent chemo preventative agents
Source: Figshare

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