859
Views
13
CrossRef citations to date
0
Altmetric
Original Articles

DCC-assisted direct esterification of phosphinic and phosphoric acids with O-nucleophiles

, , , , , & show all
Pages 239-244 | Received 24 Jul 2017, Accepted 11 Oct 2017, Published online: 13 Nov 2017
 

GRAPHICAL ABSTRACT

ABSTRACT

A novel and efficient dicyclohexylcarbodiimide-promoted protocol for the selective and controllable esterification of P(O)OH compounds using O-nucleophiles (alcohols and phenols) as efficient esterification reagents is described. This method features a high efficiency and good functional-group tolerance, meaning a simple way to synthesize a broad spectrum of phosphinic and phosphoric acid esters from basic starting materials with moderate to excellent yields.

Acknowledgment

This work was supported by National Natural Science Foundation of China (21606080, 21676077, 21476068), Scientific Research Fund of Hunan Provincial Education Department (16B111).

Additional information

Funding

National Natural Science Foundation of China(10.13039/501100001809, 21476068, 21606080, 21676077), Scientific Research Fund of Hunan Provincial Education Department, 16B111)

Reprints and Corporate Permissions

Please note: Selecting permissions does not provide access to the full text of the article, please see our help page How do I view content?

To request a reprint or corporate permissions for this article, please click on the relevant link below:

Academic Permissions

Please note: Selecting permissions does not provide access to the full text of the article, please see our help page How do I view content?

Obtain permissions instantly via Rightslink by clicking on the button below:

If you are unable to obtain permissions via Rightslink, please complete and submit this Permissions form. For more information, please visit our Permissions help page.