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Original Articles

Synthesis and characterization of a cyclometallated palladium(II) complex with (2-diphenylphosphino)ethylamine

, , &
Pages 440-441 | Received 05 Sep 2018, Accepted 14 Sep 2018, Published online: 22 Feb 2019
 

Abstract

Reaction of commercially available Ph2PCH2CH2NH2 with {PdCl(C9H12N)}2 (2:1) in CH2Cl2 afforded, instead of Pd(Cl)(P-Ph2PCH2CH2NH2)(C9H12N) 1, the cationic complex [Pd(P,N-Ph2PCH2CH2NH2)(C9H12N)]Cl 2 which was characterized by single crystal X-ray crystallography. The lack of reactivity of 2 towards Rhodamine 6G can therefore be rationalized.

Graphical Abstract

Acknowledgment

We thank the UK National Crystallography Service at the University of Southampton for data collection for 2.

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