Luminescent complexes of 1,5-diaza-3,7-diphosphacyclooctanes with coinage metals

Andrey A. KarasikArbuzov Institute of Organic and Physical Chemistry, FRC Kazan Scientific Center of RAS, Kazan, RussiaCorrespondence[email protected]

Igor D. StrelnikArbuzov Institute of Organic and Physical Chemistry, FRC Kazan Scientific Center of RAS, Kazan, Russia

Elvira I. MusinaArbuzov Institute of Organic and Physical Chemistry, FRC Kazan Scientific Center of RAS, Kazan, Russia

Irina R. DayanovaArbuzov Institute of Organic and Physical Chemistry, FRC Kazan Scientific Center of RAS, Kazan, Russia

Julia G. ElistratovaArbuzov Institute of Organic and Physical Chemistry, FRC Kazan Scientific Center of RAS, Kazan, Russia

Asiya R. MustafinaArbuzov Institute of Organic and Physical Chemistry, FRC Kazan Scientific Center of RAS, Kazan, Russia

Oleg G. SinyashinArbuzov Institute of Organic and Physical Chemistry, FRC Kazan Scientific Center of RAS, Kazan, Russia

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Abstract

Cyclic aminomethylphosphines in general and 1,5-diaza-3,7-dihposphacyclooctanes in particular are widely used for the design of d¹⁰-metal complexes with catalytic or luminescent properties. 1,5-Diaza-3,7-diphosphacyclooctanes are chelating ligands towards Ni subgroup metals and chelating or bridging ligands towards copper subgroup metals. These ligands can be utilized for the design of polynuclear complexes with stimuli-responsive luminescence. Nowadays several complexes based on 1,5-diaza-3,7-diphosphacyclooctanes demonstrating stimuli-response of emission towards organic substrates or temperature are known. Some of the gold(I) complexes are able to sensitize the luminescent anionic rhenium cluster. Copper(I) complexes display rather strong luminescence with quantum yields 20-40%.

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Luminescent complexes of 1,5-diaza-3,7-diphosphacyclooctanes with coinage metals

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Luminescent complexes of 1,5-diaza-3,7-diphosphacyclooctanes with coinage metals

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