Advanced search
Publication Cover
Phosphorus, Sulfur, and Silicon and the Related Elements Volume 194, 2019 - Issue 4-6: Proceedings of the 2018 International Conference on Phosphorus Chemistry, ICPC-22
Submit an article Journal homepage
299
Views
1
CrossRef citations to date
0
Altmetric
Original Articles

Solvent-free N-alkylation of 1,3,5-triaza-7: phospha-adamantane (PTA)

Antal UdvardyDepartment of Physical Chemistry, University of Debrecen, Debrecen, Hungary; Correspondence[email protected]
,
Csenge Tamara SzolnokiDepartment of Physical Chemistry, University of Debrecen, Debrecen, Hungary;
,
Ferenc JoóDepartment of Physical Chemistry, University of Debrecen, Debrecen, Hungary; ;MTA-DE Redox and Homogeneous Catalytic Reaction Mechanisms Research Group, University of Debrecen, Debrecen, Hungary
&
Ágnes KathóDepartment of Physical Chemistry, University of Debrecen, Debrecen, Hungary;
Pages 469-470 | Received 06 Sep 2018, Accepted 11 Oct 2018, Published online: 17 Feb 2019
 
Sample our Physical Sciences journals, sign in here to start your FREE access for 14 days

Abstract

1,3,5-triaza-7-phosphaadamantane was alkylated under solvent-free conditions with CH3I, CH3-(CH2)3-Br, Br-(CH2)4-Br, OH-CH2-CH2Br, and CH3CH2OOCCH2Br in a planetary ball mill with yields over 90%. Due to spontaneous resolution, both 1-(2-ethoxy-2-oxoethyl)-3,5-diaza-1-azonia-3,5-diaza-7-phosphaadamantane bromide (4) and (4-bromobutyl)-1-azonia-3,5-diaza-7-phosphaadamantane bromide (5) were obtained in the solid state as conglomerates of enantiomorphic crystals.

GRAPHICAL ABSTRACT

Reprints and Corporate Permissions

Please note: Selecting permissions does not provide access to the full text of the article, please see our help page How do I view content?

To request a reprint or corporate permissions for this article, please click on the relevant link below:

Order Reprints Request Corporate Permissions

Academic Permissions

Please note: Selecting permissions does not provide access to the full text of the article, please see our help page How do I view content?

Obtain permissions instantly via Rightslink by clicking on the button below:

Request Academic Permissions

If you are unable to obtain permissions via Rightslink, please complete and submit this Permissions form. For more information, please visit our Permissions help page.

Related Research Data

Solvent-free N-alkylation of 1,3,5-triaza-7: phospha-adamantane (PTA)
Source: Figshare
Solvent-free N-alkylation of 1,3,5-triaza-7: phospha-adamantane (PTA)
Source: Figshare

Linking provided by 

Related research

People also read lists articles that other readers of this article have read.

Recommended articles lists articles that we recommend and is powered by our AI driven recommendation engine.

Cited by lists all citing articles based on Crossref citations.
Articles with the Crossref icon will open in a new tab.