Electrochemical phosphorylation of arenes catalyzed by cobalt under oxidative and reductive conditions

S. O. StrekalovaArbuzov Institute of Organic and Physical Chemistry, FRC Kazan Scientific Center of RAS, Kazan, Russia

V. V. GrinenkoArbuzov Institute of Organic and Physical Chemistry, FRC Kazan Scientific Center of RAS, Kazan, RussiaCorrespondence[email protected]

http://orcid.org/0000-0001-9235-3089

T. V. GryaznovaArbuzov Institute of Organic and Physical Chemistry, FRC Kazan Scientific Center of RAS, Kazan, Russia

http://orcid.org/0000-0002-8076-8540

A. I. KononovArbuzov Institute of Organic and Physical Chemistry, FRC Kazan Scientific Center of RAS, Kazan, Russia

http://orcid.org/0000-0002-2038-537X

E. L. DolengovskiArbuzov Institute of Organic and Physical Chemistry, FRC Kazan Scientific Center of RAS, Kazan, Russia

http://orcid.org/0000-0001-5745-3738

Y. H. BudnikovaArbuzov Institute of Organic and Physical Chemistry, FRC Kazan Scientific Center of RAS, Kazan, Russia

Abstract

Catalyst capable to operate in cathode and anode spaces simultaneously was found. Electrochemical regeneration of active form of catalyst Co²⁺bpy (1%) under oxidative as well as reductive conditions allows the C–H/P–H coupling of dialkyl-H-phosphonate and various aromatic or heteroaromatic compounds.

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Acknowledgements

The authors gratefully acknowledge the Russian Science Foundation No 14-23-00016 for financial support.

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Electrochemical phosphorylation of arenes catalyzed by cobalt under oxidative and reductive conditions

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Electrochemical phosphorylation of arenes catalyzed by cobalt under oxidative and reductive conditions

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