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Phosphorus, Sulfur, and Silicon and the Related Elements Volume 194, 2019 - Issue 4-6: Proceedings of the 2018 International Conference on Phosphorus Chemistry, ICPC-22
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Original Articles

New 2,2'-bipyridine and 1,10-phenanthroline based nickel(II) phosphates

Zufar N. GafurovArbuzov Institute of Organic and Physical Chemistry of FRC Kazan Scientific Center of RAS, Kazan, Russian Federation; ;Kazan Federal University, Kazan, Russian FederationView further author information
,
Alexey B. DobryninArbuzov Institute of Organic and Physical Chemistry of FRC Kazan Scientific Center of RAS, Kazan, Russian Federation; View further author information
,
Il’yas F. SakhapovArbuzov Institute of Organic and Physical Chemistry of FRC Kazan Scientific Center of RAS, Kazan, Russian Federation; View further author information
,
Alexey A. KagilevKazan Federal University, Kazan, Russian FederationView further author information
,
Artyom O. KantyukovKazan Federal University, Kazan, Russian FederationView further author information
,
Alexey A. BalabaevKazan Federal University, Kazan, Russian FederationView further author information
,
Asiya V. ToropchinaKazan Federal University, Kazan, Russian FederationView further author information
,
Oleg G. SinyashinArbuzov Institute of Organic and Physical Chemistry of FRC Kazan Scientific Center of RAS, Kazan, Russian Federation; View further author information
&
Dmitry G. YakhvarovArbuzov Institute of Organic and Physical Chemistry of FRC Kazan Scientific Center of RAS, Kazan, Russian Federation; ;Kazan Federal University, Kazan, Russian FederationCorrespondence[email protected]
View further author information
 show all
Pages 517-521 | Received 30 Sep 2018, Accepted 02 Oct 2018, Published online: 17 Feb 2019
 
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Abstract

The reactivity of phosphoric acid (H3PO4) toward 2,2'-bipyridine (bpy) and 1,10-phenanthroline (phen) nickel dibromide complexes [NiBr2(bpy)2] and [NiBr2(phen)2] has been investigated. It was found that this interaction leads to new nickel phosphate complexes [Ni(HPO4)(bpy)2] and [Ni(HPO4)(phen)2]. X-ray crystal structure analysis of the obtained complexes indicates that the nickel ions have a distorted octahedral coordination and doubly bridged by two oxygen atoms of the phosphate moiety.

Graphical Abstract

Disclosure statement

No potential conflict of interest was reported by the authors.

Additional information

Funding

This work was supported by the Russian Science Foundation under Grant 18-13-00442.

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