Synthesis of organophosphates starting from α-hydroxyphosphonates

Nóra Z. Kiss Department of Organic Chemistry and Technology, Budapest University of Technology and Economics , Budapest, Hungary; Correspondence[email protected]

Zita Rádai Department of Organic Chemistry and Technology, Budapest University of Technology and Economics , Budapest, Hungary;

Réka Szabó Department of Organic Chemistry and Technology, Budapest University of Technology and Economics , Budapest, Hungary;

Youness Aichi Laboratoire de Chimie Physique Catalyse et Environnement (LCPCE), Faculty of Sciences Ben M’sik, Hassan II University of Casablanca , Casablanca, Morocco

Laila Laasri Laboratoire de Chimie Physique Catalyse et Environnement (LCPCE), Faculty of Sciences Ben M’sik, Hassan II University of Casablanca , Casablanca, Morocco

Said Sebti Laboratoire de Chimie Physique Catalyse et Environnement (LCPCE), Faculty of Sciences Ben M’sik, Hassan II University of Casablanca , Casablanca, Morocco

Abstract

α-Hydroxyphosphonates were successfully converted to the corresponding phosphates applying the phospha-Brook rearrangement under phase transfer catalytic conditions. Among several possible catalysts tested, K₂CO₃, Cs₂CO₃, as well as modified Moroccan phosphates were found to be suitable.

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Synthesis of organophosphates starting from α-hydroxyphosphonates

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Synthesis of organophosphates starting from α-hydroxyphosphonates

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