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Phosphorus, Sulfur, and Silicon and the Related Elements Volume 194, 2019 - Issue 4-6: Proceedings of the 2018 International Conference on Phosphorus Chemistry, ICPC-22
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Original Articles

Isomerization and application of phospholene oxides

Réka HerbayDepartment of Organic Chemistry and Technology, Budapest University of Technology and Economics, Budapest, HungaryCorrespondence[email protected]
,
Nikolett PéczkaDepartment of Organic Chemistry and Technology, Budapest University of Technology and Economics, Budapest, Hungary
,
Gábor GyörkeDepartment of Organic Chemistry and Technology, Budapest University of Technology and Economics, Budapest, Hungary
,
Péter BagiDepartment of Organic Chemistry and Technology, Budapest University of Technology and Economics, Budapest, Hungary
,
Elemér FogassyDepartment of Organic Chemistry and Technology, Budapest University of Technology and Economics, Budapest, Hungary
&
György KeglevichDepartment of Organic Chemistry and Technology, Budapest University of Technology and Economics, Budapest, Hungary
Pages 610-613 | Received 28 Sep 2018, Accepted 24 Nov 2018, Published online: 30 Dec 2018
 
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Abstract

In this research, an investigation of the isomerization and the applications of 3-phospholene oxides were elaborated. The isomerization of 3-phospholene oxides to 2-phospholene oxides was investigated under thermal condition. The application of bases and acids was also tested in this reaction. Moreover, the isomerization was also elaborated via the formation of halophosphonium salt intermediates. The 3-phospholene oxides were deoxygenated and transformed to the corresponding palladium complexes.

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