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Original Articles

Electrochemical properties of poly([Eu or Dy or Y] 1,1′-ferrocenediyl-bis(H-phosphinates))

, , , , &
Pages 1010-1012 | Received 21 May 2019, Accepted 07 Jun 2019, Published online: 22 Jul 2019
 

Abstract

Metal-organic frameworks [M2L3]n have been synthesized using ferrocene-based ligand bearing phosphinic groups L = 1,1′-ferrocenediyl-bis(H-phosphinic acid)) and M(III) = Eu, Dy, Y. Structures of complexes 13 are studied by TG, IR and powder XRD analyses and shown to be isomorphic. The redox properties of the CPs 1–3 were studied.

Graphical Abstract

Additional information

Funding

This research was supported by the Russian Foundation for Basic Research and the government of the Tatarstan Republic, grant No. 18-43-160014. The authors gratefully acknowledge the CSF-SAC FRC KSC RAS for the registration of infrared spectra (NMR, ESI, Raman, etc).

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