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A method for preparation of chiral phosphonobenzaldehydes has been developed. 1-hydroxyphosphonates by reaction with (diethylamino)trifluorosulfurane were converted into chiral 4-(1-fluoromethyl)phosphonobenzaldehydes. The chiral phosphonobenzaldehydes were used for the synthesis of phosphotyrosine analogues.
No potential conflict of interest was reported by the authors.
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