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Phosphorus, Sulfur, and Silicon and the Related Elements Volume 197, 2022 - Issue 5-6: ICPC-23: 23rd International Conference on Phosphorus Chemistry; Guest Editors:Professor Jozef Drabowicz; Professor Piotr Kiełbasiński and Professor Tomasz Cierpiał
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Short Communication

Designing biaryl phosphacyclic ligands: their characterization and evaluation in palladium-catalyzed Suzuki-Miyaura reactions of aryl bromides and chlorides

Jairus L. Lamolaa Research Centre for Synthesis and Catalysis, Department of Chemical Sciences, University of Johannesburg, Auckland Park, South AfricaCorrespondence[email protected]
ORCID Iconhttps://orcid.org/0000-0002-7633-3966View further author information
ORCID Icon,
Paseka T. Moshapoa Research Centre for Synthesis and Catalysis, Department of Chemical Sciences, University of Johannesburg, Auckland Park, South AfricaView further author information
,
Cedric W. Holzapfela Research Centre for Synthesis and Catalysis, Department of Chemical Sciences, University of Johannesburg, Auckland Park, South AfricaView further author information
&
Munaka Christopher Maumelaa Research Centre for Synthesis and Catalysis, Department of Chemical Sciences, University of Johannesburg, Auckland Park, South Africa;b Research and Technology (R & T), Sasol, Sasolburg, South AfricaView further author information
Pages 587-592 | Received 29 Oct 2021, Accepted 24 Nov 2021, Published online: 08 Dec 2021
 
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Abstract

Efficient palladium catalyst systems based on the combination of bench stable biaryl phosphacycles and Pd(OAc)2 are described for Suzuki-Miyaura cross-coupling reactions of aryl bromides and chlorides. Notably, the electronically and sterically diametric biaryl phosphacycles allowed facile coupling of sterically hindered and heterocyclic substrates.

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Acknowledgments

We are thankful for financial support from Research Centre for Synthesis and Catalysis (UJ) and Sasol. The authors also thank Sasol for providing secondary phosphines phobane-H and Cg-H.

Additional information

Funding

We are thankful for financial support from Research Centre for Synthesis and Catalysis (UJ) and Sasol.

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Related Research Data

CCDC 2051950: Experimental Crystal Structure Determination
Source: Cambridge Crystallographic Data Centre
CCDC 2051924: Experimental Crystal Structure Determination
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