https://orcid.org/0000-0003-4767-8778
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Abstract
Sequential treatment of silica gel with tetrachlorosilane and cone-shaped tetraphosphorylated tetrahydroxy(thia)calixarenes yielded porous organo-inorganic sorbents, the surface of which is covered by spatially ordered phosphonate, phosphinate and phosphine oxide groups capable of co-operative binding of metal cations. Sorption of europium(III) by the modified silica gels was studied.
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Funding
This work was partially supported by the National Academy of Sciences of Ukraine through grant «Synthesis of selective ligands and surface modification of polymeric materials for radionuclide extraction».