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Original Articles

NEUE DARSTELLUNG, SCHWEFELINSERTION UND HYDROLYSE DER PHENYL(TRIMETHYLSILYL)STIBANE

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Pages 129-133 | Received 29 Sep 1988, Published online: 04 Oct 2006
 

Abstract

Reaction of Mg and Me3,SbCl with Ph2,SbCl or PhSbCl2, gives Ph2,SbSiMe3, (1) or PhSb(SiMe3)2, (2). Sulfur inserts into 1 to give Ph2,SbSSiMe3, (3). Products of action of S8 on 2 are 3, PhSb(SSiMe3,)2, (4), (Me3,Si)2,S, and Sb2S3. Hydrolysis or methanolysis of 1, or 2 give Ph2,SbH2 (5), or PhSbH2, (6) respectively.

Die Reaktion von Mg und Me3SiCl mit Ph2SbCl oder PhSbCl2 führt zu Ph2,SbSiMe3 (1) oder PhSb(SiMe3,)2, (2). Schwefel insertiert in 1 unter Bildung von Ph2,SbSSiMe3, (3). Produkte der Reaktion von S8, mit 2 sind 3, PhSb(SSiMe3,)2, (4), (Me3,Si)2,S und Sb2S3. Durch Hydrolyse oder Methanolyse von 1 oder 2 entstehen Ph2SbH (5) oder PhSbH2 (6).

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