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Phosphorus, Sulfur, and Silicon and the Related Elements Volume 49-50, 1990 - Issue 1-4
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Section 1: Synthesis, Structure, Stereochemistry and Reactivity of Organophosphorus Compounds

Enolization of the Phosphoryl Group

T. A. Mastryukova A.N. Nesmeyanov Institute of Organo-Element Compounds, Academy of Sciences of the USSR, Vavilov str. 28, Moscow, 117334
Pages 65-68 | Published online: 04 Oct 2006
 
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Abstract

The ability of the phosphoryl group to undergo enolization has been studied. The introduction of strongly electronegative substituents at thee α-carbon atom is shown to increase CH- acidity greately and result in the enolization of the P=O group.

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