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Phosphorus, Sulfur, and Silicon and the Related Elements Volume 49-50, 1990 - Issue 1-4
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Section 1: Synthesis, Structure, Stereochemistry and Reactivity of Organophosphorus Compounds

Reactivity and Synthetic Utility of 1,3,2λ5-Dioxaphospholanes

William T. Murray The William Rand Kenan, Jr., Laboratories of Chemistry, CB# 3290, University of North Carolina, Chapel Hill, NC, 27599-3290, U.S.A.
,
Anne Pautard-cooper The William Rand Kenan, Jr., Laboratories of Chemistry, CB# 3290, University of North Carolina, Chapel Hill, NC, 27599-3290, U.S.A.
,
Nita A. Eskew The William Rand Kenan, Jr., Laboratories of Chemistry, CB# 3290, University of North Carolina, Chapel Hill, NC, 27599-3290, U.S.A.
&
Slayton A. Evans Jr The William Rand Kenan, Jr., Laboratories of Chemistry, CB# 3290, University of North Carolina, Chapel Hill, NC, 27599-3290, U.S.A.
Pages 101-104 | Published online: 04 Oct 2006
 
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Abstract

The kinetics of Lewis acid-mediated decomposition and definitions of the synthetic applicability of 1,3,2λ5-dioxaphospholanes for (i) the syntheses of highly-hindered epoxides, and (ii) the stereospecific functionalizations of stereocenters in 1,2-diol arrays are described.

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