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Phosphorus, Sulfur, and Silicon and the Related Elements Volume 49-50, 1990 - Issue 1-4
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Section 1: Synthesis, Structure, Stereochemistry and Reactivity of Organophosphorus Compounds

Olefin Synthesis via, the Li-Derivative of N,N,N′,N′-Tetramethyldimides of Arylmethanephosphonic Acids

Jordanka Petrova Faculty of Chemistry, University of Sofia, Bulgaria
,
Snejana Momchilova Faculty of Chemistry, University of Sofia, Bulgaria
&
Marko Kirilov Faculty of Chemistry, University of Sofia, Bulgaria
Pages 173-178 | Published online: 04 Oct 2006
 
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Abstract

The high erythro-stereoselective reaction of Li-tetramethyldiamides of arylmethanephosphonic acids with carbonyl compounds is used for synthesis of (Z)-alkenes by thermolysis of the erythro-adducts as well as in acidic media.

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