Abstract
The halophilic reactions of the derivatives of PIII R3 P (R = R2N, Alk, Ar) with CCl4, having preparative signifi-cance, are studied thoroughly. As far as the compounds of R2PHlg type are concerned, at the beginning of our re-searches there was was an opinion that the interaction of R2PHlg with CC14 cannot be possible because of the low nucleophility of phosphorus. We determined for the first time that diamidochlorophosphites 1 react with CC14 at the temperature 20°C and form the compounds 2, 3.1